Some Other Terms Related to Stereoisomers

IMPORTANT

Some Other Terms Related to Stereoisomers: Overview

This topic covers concepts, such as, Properties of Enantiomers, Conditions for Conformational Isomerism, Stereocenter & Invertomerism etc.

Important Questions on Some Other Terms Related to Stereoisomers

MEDIUM
IMPORTANT

When an optically active compound is placed in a 10 dm tube, it is present 20 gm in a 200 mL solution rotates the PPL by 30o. Calculate the angle of rotation and specific angle of rotation if above solution diluted to 1 litre.

HARD
IMPORTANT

An optically pure compound X gave an α D 2 5 = + 2 0 . 0 . A mixture of X and its enantiomer Y gave α D 2 5 = + 1 0 . The ratio of X to Y in the mixture is:

MEDIUM
IMPORTANT

(+) - mandelic acid has a specific rotation of 158o. What would be the observed specific rotation of a mixture of 25% (-) - mandelic acid and 75% (+) - mandelic acid ?

MEDIUM
IMPORTANT

(+) - mandelic acid has a specific rotation of 158o. What would be the observed specific rotation of a mixture of 25% (-) - mandelic acid and 75% (+) - mandelic acid?

MEDIUM
IMPORTANT

Dextrorotatory α-pinene has a specific rotation α D 2 0 = +  51.3 . A sample of α-pinene containing both the enantiomers was found to have a specific rotation value α D 2 0 = +  30.8 . The percentages of the (+) and (-) enantiomers present in the sample are, respectively.

MEDIUM
IMPORTANT

Dextrorotatory α-pinene has a specific rotation α D 2 0 = +  51.3 . A sample of α-pinene containing both the enantiomers was found to have a specific rotation value α D 2 0 = +  30.8 . The percentages of the (+) and (-) enantiomers present in the sample are, respectively.

MEDIUM
IMPORTANT

Dextrorotatory α-pinene has a specific rotation α D 2 0 = +  51.3 . A sample of α-pinene containing both the enantiomers was found to have a specific rotation value α D 2 0 = +  30.8 . The percentages of the (+) and (-) enantiomers present in the sample are, respectively:

HARD
IMPORTANT

What common symmetry of elements if any are found in the stable chair conformer of trans-1, 2-dichlorocyclohexane?

MEDIUM
IMPORTANT

Increasing order of stability among the three main conformation (i.e. eclipse, anti, gauche) of ethylene glycol is :

EASY
IMPORTANT

The number of cis-trans isomer possible for the following compound

Question Image 

HARD
IMPORTANT

How many optically active stereoisomers are possible for butane-2, 3-diol?

EASY
IMPORTANT

Enantiomers have the same physical properties.
 
 

EASY
IMPORTANT

Question Image

The given structure represents the Z-azobenzene.

EASY
IMPORTANT

Question Image

The given structure represents the E-azobenzene.

MEDIUM
IMPORTANT

Represent the geometrical isomers of azobenzene.

EASY
IMPORTANT

Which of the following compounds will exhibit cis-trans isomerism?

MEDIUM
IMPORTANT

The number of cis-trans isomers with molecular formula C2BrClFI is